Notations and conventions in molecular spectroscopy: part 1. General spectroscopic notation

The field of Molecular Spectroscopy was surveyed in order to determine a set of conventions and symbols which are in common use in the spectroscopic literature. This document, which is Part I in a series, establishes the notations and conventions used for general spectroscopic notations and deals with quantum mechanics, quantum numbers (vibrational states, angular momentum and energy levels), spectroscopic transitions, and miscellaneous notations (e.g. spectroscopic terms). Further parts will follow, dealing inter alia with symmetry notation, permutation and permutation-inversion symmetry notation, vibration-rotation spectroscopy and electronic spectroscopy

Notations and conventions in molecular spectroscopy: part 2. Symmetry notation

The field of Molecular Spectroscopy was surveyed in order to determine a set of conventions and symbols which are in common use in the spectroscopic literature. This document, which is Part 2 in a series, establishes the notations and conventions used for the description of symmetry in rigid molecules, using the Schoenflies notation. It deals firstly with the symmetry operators of the molecular point groups (also drawing attention to the difference between symmetry operators and elements). The conventions and notations of the molecular point groups are then established, followed by those of the representations of these groups as used in molecular spectroscopy. Further parts will follow, dealing inter alia with permutation and permutation-inversion symmetry notation, vibration-rotation spectroscopy and electronic spectroscopy

The role of quenching time in the evolution of the mass-size relation of passive galaxies from the WISP survey

We analyze how passive galaxies at z $\sim$ 1.5 populate the mass-size plane as a function of their stellar age, to understand if the observed size growth with time can be explained with the appearance of larger quenched galaxies at lower redshift. We use a sample of 32 passive galaxies extracted from the Wide Field Camera 3 Infrared Spectroscopic Parallel (WISP) survey with spectroscopic redshift 1.3 $\lesssim$ z $\lesssim$ 2.05, specific star-formation rates lower than 0.01 Gyr$^{-1}$, and stellar masses above 4.5 $\times$ 10$^{10}$ M$_\odot$. All galaxies have spectrally determined stellar ages from fitting of their rest-frame optical spectra and photometry with stellar population models. When dividing our sample into young (age $\leq$ 2.1 Gyr) and old (age $>$ 2.1 Gyr) galaxies we do not find a significant trend in the distributions of the difference between the observed radius and the one predicted by the mass-size relation. This result indicates that the relation between the galaxy age and its distance from the mass-size relation, if it exists, is rather shallow, with a slope alpha $\gtrsim$ -0.6. At face value, this finding suggests that multiple dry and/or wet minor mergers, rather than the appearance of newly quenched galaxies, are mainly responsible for the observed time evolution of the mass-size relation in passive galaxies.Comment: Accepted for publication in ApJ Letters; 6 pages, 3 figures, 1 tabl

Evaluating Banking Websites Privacy Statements – A New Zealand Perspective on Ensuring Business Confidence

Because banks deal with highly personal detailed and sensitive information, they need to establish and maintain the confidence of their customers more assiduously than most other businesses. The rise of internet banking and the advantages to be gained from the garnering of personal data from websites places banks in a position to exploit customer data in a way that might infringe ethical considerations. This investigation analyses the website privacy statements of New Zealand banks in terms of the provisions of the New Zealand Privacy Act. The intention was to find an objective basis for the assessment of business integrity, to explore how confidence in electronic commerce can be assured. The investigation finds that the use of privacy legislation principles as a means of evaluating website privacy statements is revealing and convincing. It is considered that customer confidence will increasingly impact on Internet businesses, and business integrity as demonstrated by comprehensive and relevant privacy statements will go a long way to provide those assurances

Measurements of ice nucleation by mineral dusts in the contact mode

Formation of ice in Earth\u27s atmosphere at temperatures above approximately −20 °C is one of the outstanding problems in cloud physics. Contact nucleation has been suggested as a possible mechanism for freezing at relatively high temperatures; some laboratory experiments have shown contact freezing activity at temperatures as high as −4 °C. We have investigated Arizona Test Dust and kaolinite as contact nuclei as a function of size and temperature and find that the fraction of submicron particles that are active as contact ice nuclei is less than 10−3 for −18 °C and greater. We also find that the different dusts are quite distinct in their effectiveness as contact nuclei; Arizona Test Dust catalyzed freezing in the contact mode at all mobility diameters we tested at −18 °C whereas kaolinite triggered freezing only for mobility diameters of 1000 and 500 nm at that temperature

Effect of colloidal aggregation on the sedimentation and rheological properties of tank waste

Tank farm experience and work performed under the Tank Waste Treatment Science task of the Tank Waste Remediation System (TWRS) Pretreatment Technology Development Project indicate that colloidal interactions can have an enormous impact on tank waste processing. This report provides the theoretical and experimental background required to understand how such agglomeration phenomena control the sedimentation and theological behavior of colloidal tank wastes. First, the report describes the conditions under which the colloidal particles present in tank sludge are expected to aggregate. Computational models have been developed to predict solution conditions leading to agglomeration, and to predict the rate and size of aggregate growth. The models show that tank sludge should be heavily agglomerated under most baseline processing conditions. Second, the report describes models used to predict sedimentation rates and equilibrium sediment density profiles based on knowledge of agglomerate structures. The sedimentation models provide a self-consistent picture that explains the apparent discrepancies between bench-top experiments and tank-farm experience. Finally, both discrete and empirical models are presented that can be used to rationalize and predict the rheological properties of colloidal sludge suspensions. In all cases, model predictions are compared and contrasted with experimental results. The net results indicate that most of the observed behaviors of real sludges can be predicted, understood, and perhaps ultimately controlled by understanding a few key central concepts regarding agglomeration phenomena

Red Companions to a z=2.15 Radio Loud Quasar

We have conducted observations of the environment around the z=2.15 radio loud quasar 1550-269 in search of distant galaxies associated either with it or the z=2.09 CIV absorber along its line of sight. Such objects will be distinguished by their red colours, R-K>4.5. We find five such objects in a 1.5 arcmin^2 field around the quasar, with typical K magnitudes of ~20.4 and no detected R band emission. We also find a sixth object with K=19.6+/-0.3, and undetected at R, just two arcseconds from the quasar. The nature of all these objects is currently unclear, and will remain so until we have determined their redshifts. We suggest that it is likely that they are associated with either the quasar or the CIV absorber, in which case their properties might be similar to those of the z=2.38 red Ly-alpha emitting galaxies discovered by Francis et al. (1997). The small separation between the quasar and the brightest of our objects suggests that it may be the galaxy responsible for the CIV metal line absorption system. The closeness to the quasar and the red colour might have precluded similar objects from being uncovered in previous searches for emission from CIV and eg. damped absorbers.Comment: To appear in "Photometric Redshifts and High Redshift Galaxies", eds. R. Weymann, L. Storrie-Lombardi, M. Sawicki & R. Brunne

An Optical/Near-Infrared Study of Radio-Loud Quasar Environments II. Imaging Results

We use optical and near-IR imaging to examine the properties of the significant excess population of K>=19 galaxies found in the fields of 31 z=1-2 radio-loud quasars by Hall, Green & Cohen (1998). The excess occurs on two spatial scales: a component at <40'' from the quasars significant compared to the galaxy surface density at >40'' in the same fields, and a component roughly uniform to ~100'' significant compared to the galaxy surface density seen in random-field surveys in the literature. The r-K color distributions of the excess galaxy populations are indistinguishable and are significantly redder than the color distribution of the field population. The excess galaxies are consistent with being predominantly early-type galaxies at the quasar redshifts, and there is no evidence that they are associated with intervening MgII absorption systems. The average excess within 0.5 Mpc (~65'') of the quasars corresponds to Abell richness class ~0 compared to the galaxy surface density at >0.5 Mpc from the quasars, and to Abell richness class ~1.5 compared to that from the literature. We discuss the spectral energy distributions (SEDs) of galaxies in fields with data in several passbands. Most candidate quasar-associated galaxies are consistent with being 2-3 Gyr old early-types at the quasar redshifts of z~1.5. However, some objects have SEDs consistent with being 4-5 Gyr old at z~1.5, and a number of others are consistent with ~2 Gyr old but dust-reddened galaxies at the quasar redshifts. These potentially different galaxy types suggest there may be considerable dispersion in the properties of early-type cluster galaxies at z~1.5. There is also a population of galaxies whose SEDs are best modelled by background galaxies at z>2.5.Comment: Accepted to ApJ; 54 pages including 30 figures; 2 color GIF files available separately; also available from http://www.astro.utoronto.ca/~hall/thesis.htm

Thermocapillary actuation of liquid flow on chemically patterned surfaces

We have investigated the thermocapillary flow of a Newtonian liquid on hydrophilic microstripes which are lithographically defined on a hydrophobic surface. The speed of the microstreams is studied as a function of the stripe width w, the applied thermal gradient |dT/dx| and the liquid volume V deposited on a connecting reservoir pad. Numerical solutions of the flow speed as a function of downstream position show excellent agreement with experiment. The only adjustable parameter is the inlet film height, which is controlled by the ratio of the reservoir pressure to the shear stress applied to the liquid stream. In the limiting cases where this ratio is either much smaller or much larger than unity, the rivulet speed shows a power law dependency on w, |dT/dx| and V. In this study we demonstrate that thermocapillary driven flow on chemically patterned surfaces can provide an elegant and tunable method for the transport of ultrasmall liquid volumes in emerging microfluidic technologies